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The aim of work in this theme is to design and evaluate composite architectures that create ductility via geometrical rearrangement of fibre orientation, matched to tailored matrix characteristics.

For example, it has been successfully demonstrated that using Skyflex™ carbon/epoxy plies of only 0.03 mm thickness, matrix cracking and delamination can be completely suppressed in angle-ply laminates, allowing the fibres to rotate under tensile loading, creating additional strain and pseudo-ductility. Angle plies of (±45) layup can produce strains of over 20% and necking behaviour despite the brittle nature of both the fibres and matrix. There is a trade off in the stresses and strains, but modelling has allowed us to achieve a good balance of properties with thin ply (±25) carbon/epoxy laminates that gave a pseudo-ductile strain of 1.23% and a maximum stress of 927 MPa. Tests involving loading, unloading and then reloading have shown that the initial modulus is fully recovered, and so these laminates may be considered as ductile rather than pseudo-ductile.

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Angle plies

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Thin-ply angle plies allow additional strain via fibre reorientation. This can be combined with fragmentation to produce large pseudo-ductile strains and reduced notch sensitivity.

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Microbraided ropes

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Wavy ply sandwich

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Wavy ply discontinuities

buy Clomiphene and nolvadex‘Brick and mortar’ composite architectures have been investigated to produce a ductile failure process from either complete yielding of the matrix in the overlap region, or from cracks initiating at the ends and growing in towards the centre of the overlap regions.

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Ductile micro-braided helical structures

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Friction mechanisms

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Triaxial braided composites

where to buy Clomiphene in south africaTriaxial braided composites can show a highly non-linear stress-strain response with a pseudo-ductile plateau due to the complex damage behaviour. A meso-scale modelling framework was developed, which showed good correlation with the measured stress-strain curves and damage mechanisms.

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Micro-wrapped hybrid tows

Uni-directional woven fabric laminates consisting of micro-wrapped tows have been produced.  While conventional hybrids exhibited a significant load-drop after the first failure, micro-wrapped laminates exhibited pseudo-ductility through stable fibre fragmentation/ pull-out.

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The theme aims to design and evaluate aligned fibre approaches that achieve a ductile or pseudo-ductile response, while maintaining strength and stiffness. This theme explores hybridisation, aligned discontinuous fibre architectures and fibre surface modifications that promote slip at the interface. Some of these approaches are summarised here:

Ductility via fragmentation

One strategy in this theme involves fragmentation in thin-ply hybrids. Again there is a trade-off between pseudo-ductility and yield stress. A range of different glass-carbon hybrid configurations has been evaluated, and pseudo-ductile strains of up to 2.66% have been obtained with a plateau stress of 520 MPa, or 0.86% pseudo-ductile strain with a plateau stress of over 1300 MPa. Similar responses have also been achieved with carbon-carbon hybrids. However in both cases, loading-unloading-reloading tests show a reduction in initial modulus due to the damage, and so these laminates show pseudo-ductility rather than true ductility.

Ductility via fragmentation in thin angle plies with 0˚ plies

The two previous mechanisms can be combined by replacing the lower modulus glass plies in a glass/carbon hybrid with carbon fibre angle plies. This allows the fragmentation mechanism exhibited by the unidirectional hybrid composites to occur in the 0˚ plies together with the fibre rotation of the angle plies. For example [±26₅/0]_S laminates of Skyflex thin carbon/epoxy gave a pseudo-ductile strain of 2.2%.

Discontinuous fibre composites

Another mechanism for pseudo-ductility is slip at the interfaces between discontinuous fibres or plies. This has been demonstrated in model systems of discontinuous carbon/epoxy prepreg where the plies have been cut through the thickness prior to layup. The effect of ply thickness, cut spacing and alignment on the response have been investigated both numerically and experimentally. For example specimens of IM7/8552 carbon/epoxy with 0.25 mm thick discontinuous ply blocks (0.125 mm for surface plies) and overlap length of about 8 mm were tested and showed significant non-linearity, providing a clear indication of damage, with a modest pseudo-ductile strain of 0.25%.

Non-linear tensile behaviour can also be produced in short fibre composites. The HiPerDiF method allows manufacture of high volume fraction well aligned unidirectional short fibre composites. When high-modulus carbon and glass fibres are mixed, non-linear response and pseudo-ductility can be obtained similar to that achieved with thin plies. The HiPerDiF method is explained in more detail buy Clomiphene and hcg online.

Final reports

Hybrids – Intermingled fibre types

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Thin-ply Pseudo-ductile Hybrids

can i buy Clomiphene at rite aidA new failure mechanism of fragmentation in hybrid thin-ply laminates has been demonstrated which gives a pseudo-ductile stress-strain response. This allows load redistribution at stress concentrations, greatly reducing notch sensitivity, and can also be used as a visual overload indicator.

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Discontinuous pre-preg

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Discontinuous fibre manufacturing

order Clomiphene online with mastercardThe High Performance Discontinuous Fibre (HiPerDiF) technology allows to produce aligned discontinuous fibre reinforced composites with mechanical properties comparable to those of continuous fibre composite, by exploiting the sudden momentum change of a jet of fibres suspended in water directed in a narrow gap between parallel plates.

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Laser modified fibres

can you purchase Clomiphene over the counterUnduloid-reinforcing carbon fibres were produced using controlled laser irradiation which resulted in expanded and ablated regions along the fibre axis. When embedded into a compliant matrix, extensive ploughing from the tapered ends contributed to a ~7 fold increase in work of pull-out.

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Hierarchical bundle composites

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Interlaminar and ply weakening

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Discontinuous composites across the scales

buy Clomiphene online ukA semi-analytical virtual testing framework was developed to predict the response of aligned discontinuous composites with single and hybrid fibre-types, as produced by the HiPerDiF manufacturing process. This framework can be used to model full specimens (with millions of fibres) within minutes, and its predictions have been compared against experiments.

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This theme aims to design composite constituents that will enable new mechanisms for ductility, whilst retaining high strength and stiffness. These will ultimately be integrated with novel architectures to produce high performance composites with a ductile response.

One example of this is the work we have undertaken with Cellulose nanocrystals (CNCs). Despite their promise, mechanical properties of CNC/polymer composites, especially in terms of tensile strength and Young’s modulus, have often been limited.

High loadings of water-soluble CNCs were well dispersed in poly vinyl alcohol (PVOH) to form coagulation spinning dopes for composite fibres. The resulting CNC/PVOH composite fibres showed significantly increased yield strength and Young’s modulus for all fibres, compared with PVOH fibres. The 40 wt.% of CNC/PVOH showed the highest Young’s modulus (29.6 ± 4.2 GPa) and tensile strength (0.85 ± 0.06 GPa) with a strain-to-failure of 5.6 ± 0.2 %. The graph shows that incorporation of CNC into the PVOH matrix increased the tensile strength and Young’s modulus, and the PVOH fibre become tougher and more resistant to deformation in the presence of CNC:

Final reports

High performance ductile fibres

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Nacre-inspired interphase

buy Clomiphene pct ukA nanostructured coating was developed with ~ 90 wt% of well aligned inorganic platelets embedded in a polymer matrix. Fibres were successfully coated, showing reduced local stress concentrations at fiber breaks and increased extent of fibre slippage.

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Aerogel modified matrices

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Carbon Nanotube Fibres and Sheets

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Optimised Matrices

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Ductile Superlattice Nanoparticle Matrices

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